I. Adhesion Failure (Cross-Cut Test <3B)
Failure Mechanism:
Mismatch between PET surface energy (38–42mN/m) and water-based ink surface energy (45–50mN/m) leads to contact angle >65°.
Solutions:
- Substrate Pretreatment
- Corona treatment: Dyne level increased to 54–56mN/m (power 8–10kW, speed 80m/min).
- Primer coating: Water-based polyesterurethane primer (dry film thickness 0.8–1.2μm).
- Ink Formulation OptimizationComponentSpecificationFunctionModified polyurethane dispersionShore A 75–80 hardnessMain film-forming resinEpoxy-grafted acrylate8–12% additionCrosslinking enhancementCarbodiimide-based crosslinker0.5–1.5% (post-cure at 60℃)Chemical bond reinforcementResult: Cross-cut test achieved 5B (ASTM D3359).
II. Low Drying Efficiency (Energy Consumption >1.8kW·h/kg)
Issue Analysis:
Latent heat of evaporation for water-based systems (2257kJ/kg) is 2.3× higher than solvent-based inks.
Efficiency Improvement:
| Technology | Parameters | Energy Saving |
|---|---|---|
| Infrared-hot air drying | 80℃/5s → 110℃/8s | 40% energy reduction |
| Microwave-assisted drying | 2450MHz/300W | 2.5× faster drying |
| Cosolvent optimization | 2–3% diethylene glycol butyl ether | 35% evaporation rate increase |
III. Printing Levelling Defects (Orange Peel Index >0.25)
Root Cause:
Dynamic surface tension >32mN/m results in spreading coefficient <0.8.
Improvements:
- Rheology Control Agents
- Hydrophobically modified alkali-swellable thickener (HASE) at 0.3–0.6%.
- Thixotropy index controlled at 1.8–2.2 (Brookfield DV3T).
- Process Optimization
- Printing viscosity: Flexo 18–22s / Gravure 12–15s (Ford Cup, 25℃).
- Environmental control: 25±2℃, 55±5% RH.
IV. Poor Resistance (Ethanol Rubs <20)
Enhancement Strategies:
| Approach | Components | Performance Outcome |
|---|---|---|
| Chemical crosslinking | Silicone-modified polyurethane (15%) + aziridine crosslinker (0.8–1.2%, pH 8.5–9.0) | Ethanol rubs >200 (GB/T 13217.7) |
| Physical reinforcement | Nano SiO₂ aerogel (3–5%) | Abrasion resistance ×4 |
V. Static Electricity Buildup (Surface Resistance >10¹³Ω)
Safety Risk:
Static voltage up to 15kV poses fire hazard (NFPA 77).
Anti-Static Solutions:
- Ink Modification
- Ionic liquid-based antistatic agent (0.5–1.0%, resistivity <10⁹Ω·□).
- Carbon nanotubes (0.3–0.5%, volume resistivity 10³Ω·cm).
- Equipment Upgrades
- Install static eliminators (±5kV balance control).
- Grounding system impedance <4Ω (IEC 61340).
VI. Color Variation (ΔE >2.0)
Control System:
- Pigment Standardization
- Particle size D90 <1μm (laser diffraction).
- Color concentration variation <±1.5% (spectrodensitometer).
- Process Monitoring
- Online colorimeter (30cm interval, feedback to ink supply).
- Automatic viscosity compensation (±0.5s tolerance).
VII. Laminating Strength Degradation (Peel Force <1.5N/15mm)
Preventive Measures:
- Interface Strengthening
- Primer-type water-based adhesive (3.5–4.5g/㎡ coating).
- Plasma treatment (1000W power, 20m/min speed).
- Ink Compatibility
- Avoid direct contact between carboxyl-containing resins and amine-based curing agents.
- Curing conditions: 50℃/48h, 60% RH.

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